KUSUKAWA Takahiro

FacultyMolecular Chemistry and Engineering
PositionAssociate Professor
Last Updated :2021/09/16

Profile

Degree

  • 1995/03

Campus Career

  • 2003/04-2007/03, Kyoto Institute of Technology, Associate Professor
  • 2007/04-, Kyoto Institute of Technology, Associate Professor
  • Homepage

    Educational Activities

    Classes

    • Organic Chemistry Ⅱ
    • Organic Reactions
    • Control in Organic Chemistry
    • Stereochemical Aspects in Synthetic Organic Chemistry, Advanced

    Syllabus

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    Research Activities

    Papers

    • Recognition of dicarboxylic acids and diphosphonic acids using anthracene-based diamidine: formation of amidinium-carboxylate and amidinium-phosphonate salt bridges in a protic solvent
      Author : Takahiro Kusukawa, Keita Nakaguchi, Saya Nishimura and Akane Nakajima
      Journal : Supramol. Chem.
      Publication Date : 2021
      Volume,Number,Page : 2021 in press
    • Charge-Transfer-Adaptable Double-Strand Formation of Porphyrin–BODIPY–Porphyrin Triad
      Author : Mitsuhiko Morisue,* Miho Kawanishi, Takahiro Kusukawa
      Journal : ChemPhotoChem
      Publication Date : 2021
      Volume,Number,Page : 2021 in press
    • Biobased poly(itaconic acid-co-10-hydroxyhexylitaconic acid)s: synthesis and thermal characterization
      Author : Yuji Aso, Mei Sano, Ryoki Yada, Tomonari Tanaka, Takashi Aoki, Hitomi Ohara, Takahiro Kusukawa, Keiji Matsumoto, Kazuhito Wada
      Journal : Materials
      Publication Date : 2020/06
      Volume,Number,Page : 13巻12号
    • Dipyrrin Complexes of Borasiloxane Silanols with Adaptive Hydrogen-Bonded Conformations in the Crystal and in Solution States
      Author : Mitsuhiko Morisue,* Takahiro Kusukawa, Seiji Watase
      Journal : Eur. J. Inorg. Chem
      Publication Date : 2020/04
      Volume,Number,Page : doi: 10.1002/ejic.202000118
    • Microbial Screening Based on the Mizoroki-Heck Reaction Permits Exploration of Hydroxyhexylitaconic-Acid-Producing Fungi in Soils
      Author : Mei Sano, Ryoki Yada; Yusuke Nomura; Tomonari Tanaka; Hitomi Ohara; Yuji Aso; Takahiro Kusukawa; Hiroshi Ando; Keiji Matsumoto; Kazuhito Wada
      Journal : Microorganisms
      Publication Date : 2020/04
      Volume,Number,Page : 8巻5号
    • Synthesis of an anthracene-based diguanidine and its recognition of carboxylic acids and phosphonic acids
      Author : Takahiro Kusukawa∗, Ryosuke Mura, Yasuhiro Ohtagaki, Masashi Ooe
      Journal : Tetrahedron
      Publication Date : 2020/03
      Volume,Number,Page : 76巻6号131065
    • Mechanofluorochromic Properties of 1,8-Diphenylanthracene Derivatives
      Author : Takahiro Kusukawa,* Yusuke Kojima, and Fumihiro Kannen
      Journal : Chem. Lett.
      Publication Date : 2019/10
      Volume,Number,Page : 48巻・10号・1213-1216
    • Carboxylic acid recognition of diamidine having a fluorescent 1,8-diphenylanthracene unit and its detection of amidinium-carboxylate and amidinium formation
      Author : Takahiro Kusukawa∗, Hiroki Aramoto, Takehiro Umeda, Yusuke Kojima
      Journal : Tetrahedron
      Publication Date : 2019/01
      Volume,Number,Page : 2019, 75, 1293-1305
    • A Turn-on Fluorescence Sensor for Dicarboxylic Acids Based on Aggregation-Induced Emission
      Author : Takahiro Kusukawa*, Eyob Ashenafi Tessema and Yuki Hoshihara
      Journal : Chem. Lett.
      Publication Date : 2018/11
      Volume,Number,Page : 47, 1395-1398
    • Turn-on fluorescence sensor for mono- and di-phosphonic acid derivatives using anthracene-based diamidine and its detection of amidinium-phosphonate and amidinium formation
      Author : Takahiro Kusukawa*, Hitoshi Nagano, Keita Nakaguchi, Shota Takeshita, Yuya Harumoto
      Journal : Tetrahedron
      Publication Date : 2018/01
      Volume,Number,Page : 74巻, 4号, p465-476
    • Dicarboxylic Acid Recognition of 1,8-Bis(N,N’-diethylamidino)anthracne: NMR, X-ray, ESI-mass and Fluorescence Analyses of Dicarboxylic Acid Binding Complexes
      Author : Takahiro Kusukawa, Kouta Inoue Hiroaki Obata, Ryosuke Mura
      Journal : Tetrahedron
      Publication Date : 2017/02
      Volume,Number,Page : 73巻 6号 661-670
    • Enhancement of the Catalytic Activity of Chiral H8-BINOL Titanium Complexes by Introduction of Sterically Demanding Groups at the 3-Position
      Author : Yasuki Hayashi, Nobuaki Yamamura, Takahiro Kusukawa, and Toshiro Harada
      Journal : Chem. Eur. J.
      Publication Date : 2016/08
      Volume,Number,Page : 22巻, 34号, 12095 –12105
    • Formation of Discrete Ladders and a Macroporous Xerogel Film by the Zipperlike Dimerization of Meso–Meso-Linked Zinc(II) Porphyrin Arrays with Di(pyrid-3-yl)acetylene
      Author : K. Kose, J. Motoyanagi, T. Kusukawa, A. Osuka, A. Tsuda
      Journal : Angew. Chem. Int. Ed
      Publication Date : 2015/06
      Volume,Number,Page : 54, 8673–8678
    • Fluorescent detection of amidiniumu-carboxylate and amidinium formation using a 1,8-diphenyl- naphthalene-based diamidine: dicarboxylic acid recognition with high fluorescence efficiency
      Author : 楠川隆博, 田中脩吾, 井上皓太
      Journal : Tetrahedron
      Publication Date : 2014/07
      Volume,Number,Page : 70, 4049-4056
    • Four-component assembly in the crystalline state driven by amidinium-carboxylate salt bridge formation from an aqueous solution
      Author : 楠川 隆博, Matsumoto Kazuya, Nakamura Hajime, Iizuka Wartaru, Toyama Keisuke, Takeshita Shota
      Journal : Organic & Biomolecular Chemistry
      Publication Date : 2013/05
      Volume,Number,Page : 11巻 3692-3698ページ
    • Observation of a Hydrogen-Bonded 3D Structure of Crystalline Glycerol
      Author : Takahiro Kusukawa, Niwa Genki, Sasaki Takato, Oosawa Ryosuke, Himeno Wataru, Kato Masahiro
      Journal : Bulletin of the Chemical Society of Japan
      Publication Date : 2013/03
      Volume,Number,Page : 86巻 3号
    • A triangular prismatic hexanuclear iridium(III) complex bridged by flavin analogues showing reversible redox processes
      Author : Yuji Inui, Motoo Shiro, Takahiro Kusukawa, Shunichi Fukuzumi, Takahiko Kojima
      Journal : Dalton Transactions
      Publication Date : 2013/02
      Volume,Number,Page : 42巻 2273-2278ページ
    • Fluorescent detection of amidinium-carboxylate and amidinium formation using anthracene-based diamidine: an application for the analysis of dicarboxylic acid binding
      Author : Takahiro Kusukawa, Keisuke Toyama, Shota Takeshita, Syugo Tanaka
      Journal : Tetrahedron
      Publication Date : 2012/12
      Volume,Number,Page : 68巻 9973-9981ページ
    • Formation and characterization of water-soluble hetero capsules derived from multiple ionic interactions
      Author : Takahiro Kusukawa, Chikako Katano, Chizuru Kim
      Journal : Tetrahedron
      Publication Date : 2012/02
      Volume,Number,Page : 68巻 1492-1501ページ
    • Alkylative Carbocyclization of ω-Iodoalkynyl Tosylates with Alkynyllithium Compounds Through a Carbenoid-Chain Process Leadung to (1-Iodoprop-2-ynylidene)tetrahydrfurans and -cycloprppanes.
      Author : 原田俊郎, 今岡大輔, 北野千絵, 楠川 隆博
      Journal : Chem. Eur. J.
      Publication Date : 2010/07
      Volume,Number,Page : 16, 9164-9174
    • A Discrete Supramolecular Conglomerate Composed of Two Saddle-Distorted Zinc(II)-Phthalocyanine Complexes and a Doubly Protonated Porphyrin with Saddle Distortion Undergoing Efficient Photoinduced Electron Transfer
      Author : T. Kojima, T. Honda, K. Ohkubo, M. Shiro, T. Kusukawa, T. Fukuda, N. Kobayashi, S. Fukuzumi
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2008/02
      Volume,Number,Page : 47, 6712-6716
    • Development of Highly Enantioselective Oxazaborolidinone Catalysts for the Reactions of Acyclic α,β-Unsaturated Ketones
      Author : Toshiro Harada, Takahiro Kusukawa
      Journal : Synlett
      Publication Date : 2007/01
      Volume,Number,Page : 1823
    • Endohedral Clusterization of Ten Water Molecules into a "Molecular Ice" within the Hydrophobic Pocket of a Self-Assembled Cage
      Author : M. Yoshizawa, T. Kusukawa, M. Kawano, T. Ohhara, I. Tanaka, K. Kurihara, N. Niimura, *M. Fujita
      Journal : J. Am. Chem. Soc.
      Publication Date : 2005/00
      Volume,Number,Page : 127・1798-2799
    • High Facial Selectivity Observed in Amine Coordination to Chiral Oxazaborolidinone
      Author : *T. Harada, Y. Yamamoto, T. Kusukawa
      Journal : Chem. Commun.
      Publication Date : 2005/00
      Volume,Number,Page : 859-861
    • Phenyl trifluorovinyl sulfide: a radical acceptor for preparation of gem-difluoromethylene compounds.
      Author : *T. Okano, M. Chokai, M. Hiraishi, M. Yoshizawa, T. Kusukawa, M. Fujita
      Journal : Tetrahedron
      Publication Date : 2004/00
      Volume,Number,Page : 60・4031-4035
    • Complementary Multicomplexation of Desymmetrized 2,2’-Bipyridine Ligands on Square Planar Pd(II) Centers
      Author : M. Tominaga, T. Kusukawa, S. Sakamoto, K. Yamaguchi, *M.Fujita
      Journal : Chem. Lett.
      Publication Date : 2004/00
      Volume,Number,Page : 33・794-795
    • A Palladium(II)-Clipped Aromatic Sandwich
      Author : K. Kumazawa, Y. Yamanoi, M. Yoshizawa, T. Kusukawa, *M. Fujita
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2004/00
      Volume,Number,Page : 43・5936-5940
    • A circular tris[2]catenane from molecular figure of eight
      Author : A. Hori, K. Yamashita, T. Kusukawa, A. Akasaka, K. Biradha, *M. Fujita
      Journal : Chem. Commun.
      Publication Date : 2004/00
      Volume,Number,Page : 1798-1799
    • Finite, Spherical Coordination Networks that Self-Organize from 36 Small Components
      Author : M. Tominaga, K. Suzuki, M. Kawano, T. Kusukawa, T. Ozeki, S. Sakamoto, K. Yamaguchi, *M. Fujita
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2004/00
      Volume,Number,Page : 43・5621-5625
    • Remarkable Acceleration of Diels-Alder Reactions in a Self-Assembled Coordination Cage
      Author : T. Kusukawa, T. Nakai, T. Okano, *M. Fujita
      Journal : Chem. Lett.
      Publication Date : 2003/00
      Volume,Number,Page : 32・284-285
    • PdII-Directed Dynamic Assembly of a Dodecapyridine Ligand into End-Capped and Open Tubes: The Importance of Kinetic Control in Self-Assembly
      Author : S. Tashiro, M. Tominaga, T. Kusukawa, M. Kawano, S. Sakamoto, K. Yamaguchi, *M. Fujita
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2003/00
      Volume,Number,Page : 42・3267-3270
    • The polar effect on the regiochemistry of nucleophilic substitution of trifluoromethylated pi-allylpalladium complex
      Author : *T. Okano, H. Matsubara, T. Kusukawa and M. Fujita
      Journal : J. Organomet. Chem.
      Publication Date : 2003/00
      Volume,Number,Page : 676・43-48
    • Multicomponent Assembly of a Pyrazine-Pillared Coordination Cage That Selectively Binds Planar Guests by Intercalation
      Author : K. Kumazawa, K. Biradha, T. Kusukawa, T. Okano, *M. Fujita
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2003/00
      Volume,Number,Page : 42・3909-3913
    • Phenylenebis(ethynyl)-Tethered Bis-BINOL Ligands for Enantioselective Catalyst Based on Dimeric Ti(IV) Aggregate
      Author : *T. Harada, Y. Hiraoka, T. Kusukawa, Y. Marutani, S. Matsui, M. Nakatsugawa, and K. Kanda
      Journal : Org. Lett.
      Publication Date : 2003/00
      Volume,Number,Page : 5・5059-5062
    • Multicomponent matal-ligand self-assembly
      Author : W.-Y. Sun, M. Yoshizawa, T. Kusukawa, M. Fujita
      Journal : Current Opinion in Chemical Biology
      Publication Date : 2002/12
      Volume,Number,Page : 6巻・6号・p757-764
    • Self-Assembled Coordination Cages
      Author : M. Yoshizawa,Y. Takeyama, T. Kusukawa, *M. Fujita
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2002/00
      Volume,Number,Page : 41・1347-1349
    • Copper(I)-Catalyzed Addition of Trifluoromethylated Benzyl Radicals Derived from Aryltrifluoroethyl Bromides to Terminal Olefins
      Author : *T. Okano, H. Sugiura, M. Fumoto, H. Matsubara, T. Kusukawa, and M. Fujita
      Journal : J. Fluorine Chem.
      Publication Date : 2002/00
      Volume,Number,Page : 114・91-98
    • Synthesis of Optically Active Trifluoromethylated Indolizidine Derivatives via Stereoselective Radical Cyclization
      Author : *T. Okano, M. Fumoto, T. Kusukawa, and M. Fujita
      Journal : Org. Lett.
      Publication Date : 2002/00
      Volume,Number,Page : 4・1571-1573
    • Electrochemically Driven Molecule Motions of Ferrocene and its Dreivatives inside/outside of a Nanometer-Sized Coordination Cage
      Author : W.-Y. Sun, T. Kusukawa, *M. Fujita
      Journal : J. Am. Chem. Soc.
      Publication Date : 2002/00
      Volume,Number,Page : 124・11570-11571
    • A Self-Assembled M6L4?type Coordination Nanocage with 2,2’-Bipyridine Ancillary Ligands. Facile Crystallization and X-ray Analysis of Shape-Selective Enclathration of Neutral Guest in the Cage
      Author : T. Kusukawa, *M. Fujita
      Journal : J. Am. Chem. Soc.
      Publication Date : 2002/00
      Volume,Number,Page : 124・13576-13582
    • Molecular Paneling via Coordination
      Author : M. Fujita, K. Umemoto, M. Yoshizawa, N. Fujita, T. Kusukawa, K. Biradha
      Journal : Chem. Commun.
      Publication Date : 2001/02
      Volume,Number,Page : 6号・p509-518
    • Probing Guest Geometry and Dynamics through Host-Guest Interactions
      Author : T. Kusukawa, M. Yoshizawa, *M. Fujita
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2001/00
      Volume,Number,Page : 40・1879-1884
    • Characterization of Encapsulating Supramolecules by Using CSI-MS with Ionization-Promoting Reagents
      Author : S. Sakamoto, M. Yoshizawa, T. Kusukawa, *M. Fujita, K. Yamaguchi
      Journal : Org. Lett.
      Publication Date : 2001/00
      Volume,Number,Page : 3・1601-1604
    • Molecular Paneling by Coordination: An M15L6 Hexahedral Molecular Capsule having Clefts for Reversible Guest Inclusion
      Author : K. Umemoto, H. Tsukui, T. Kusukawa, K. Biradha, and M. Fujita
      Journal : Angew. Chem. Int. Ed.
      Publication Date : 2001/00
      Volume,Number,Page : 40・2620-2622
    • DOSY Study on Dynamic Catenation: Self-Assembly of a [3]Catenane as a Meta-Stable Compound from Twelve Simple Components
      Author : A. Hori, K. Kumazawa, T. Kusukawa, D. K. Chand, M. Fujita, S. Sakamoto, and K. Yamaguchi
      Journal : Chem. Eur. J.
      Publication Date : 2001/00
      Volume,Number,Page : 7・4142-4149
    • Cavity-Directed Synthesis of Labile Silanol Oligomers within Self-Assembled Coordination Cages
      Author : M. Yoshizawa, T. Kusukawa, *M. Fujita, S. Sakamoto and K. Yamaguchi
      Journal : J. Am. Chem. Soc.
      Publication Date : 2001/00
      Volume,Number,Page : 123・10454-10459
    • Dynamic Assembly of Coordination Boxes from (en)Pd(II) Unit and a Rectangular Panel-like Ligand: NMR, CSI-MS, and X-ray Studies
      Author : Y. Yamanoi, Y. Sakamoto, T. Kusukawa, *M. Fujita, S. Sakamoto, and K. Yamaguchi
      Journal : J. Am. Chem. Soc.
      Publication Date : 2001/00
      Volume,Number,Page : 123・980-981
    • ナノサイズ空間を有するかご状分子の構築と機能
      Author : 楠川隆博・藤田 誠
      Journal : 触媒
      Publication Date : 2000/08
      Volume,Number,Page : 第42巻・8号・p564-568
    • Hydrophobic Assembling of a Coordination Nanobowl into a Dimeric Capsule Which Can Accomodate up to Six Large Organic Molecules
      Author : S.-Y. Yu, T. Kusukawa, K. Biradha, *M. Fujita
      Journal : J. Am. Chem. Soc.
      Publication Date : 2000/00
      Volume,Number,Page : 122・2665-2666
    • Wacker Oxidation in an Aqueous Phase through the Reverse Phase-tansfer Catalysis of a Self-assembled Nanocage
      Author : H. Ito, *T. Kusukawa, *M. Fujita
      Journal : Chem. Lett.,
      Publication Date : 2000/00
      Volume,Number,Page : 598
    • Ship-in-a-bottle Synthesis of Otherwise Labile Cyclic Trimers of Siloxanes in a Self-assembled Coordination Cage
      Author : M. Yoshizawa, *T. Kusukawa, *M. Fujita, and K. Yamaguchi
      Journal : J. Am. Chem. Soc.
      Publication Date : 2000/00
      Volume,Number,Page : 122・6311-6312
    • "Ship-in-a-bottle" Formation of Stable Hydrophobic Dimers of cis-Azobenzene and -Stilbene Derivatives in a Self-assembled Coordination Nanocage
      Author : T. Kusukawa, M. Fujita
      Journal : J. Am. Chem. Soc.
      Publication Date : 1999/01
      Volume,Number,Page : 121巻・6号・p1397
    • Self-Assembly of Nanometer-Sized Macrotricyclic Complexes from Ten Small Component Molecules
      Author : M. Fujita, S.-Y. Yu, T. Kusukawa, H. Funaki, K. Ogura, K. Yamaguchi
      Journal : Angew. Chem. Int. Ed. Engl.
      Publication Date : 1998/12
      Volume,Number,Page : 37巻・15号・p2082-2085
    • Encapsulation of Large, Neutral Molecules in a Self-assembled Nanocage Incorporating Six Palladium(II) Ions
      Author : T. Kusukawa, M. Fujita
      Journal : Angew. Chem. Int. Ed. Engl.
      Publication Date : 1998/12
      Volume,Number,Page : 37巻・22号・p3142-3144
    • A Tris-Phenylphenol N8O3 Schiff-Base Cryptand: Structural Characterization and Fluorescence Titration for Lanthanide Coordination
      Author : S.-Y. Yu, B. Wu, X.-J Yang, W.-J Zhang, X. Wu, T. Kusukawa
      Journal : J. Phys. Org. Chem.
      Publication Date : 1998/12
      Volume,Number,Page : 11巻・12号・p903-911
    • A Thermally Switchable Molecular Lock. The Guest-Templated Synthesis of a Kinetically Stable Nanosized Cage
      Author : F. Ibukuro, T. Kusukawa, M. Fujita
      Journal : J. Am. Chem. Soc.
      Publication Date : 1998/08
      Volume,Number,Page : 120巻・33号・p8561-8562
    • Substituents Effects on the Addition of Silyllithium and Germyllithium to C60
      Author : T. Kusukawa, W. Ando
      Journal : J. Organomet. Chem.
      Publication Date : 1998/06
      Volume,Number,Page : 561巻・1-2号・p109-120
    • Photochemical Functionalizations of C60 with phenylpolysilanes
      Author : T. Kusukawa, W. Ando
      Journal : J. Organomet. Chem.
      Publication Date : 1998/05
      Volume,Number,Page : 559巻・1-2号・p11-22
    • Photochemical Reactions of Oligosilanes with C60
      Author : T. Kusukawa, W. Ando
      Journal : Organometallics
      Publication Date : 1997/09
      Volume,Number,Page : 16巻・19号・p4027-4029
    • Reactions of a C60-Substituted Benzotetrasilacyclohexane with Bromine
      Author : T. Kusukawa, K. Ohkubo, W. Ando
      Journal : Organometallics
      Publication Date : 1997/06
      Volume,Number,Page : 16巻・12号・p2746-2747
    • Reactions of Silyllithium with C60: Isolation and X-ray Crystallographic Characterization of an Unusual Bissilylated-C60 Adduct
      Author : T. Kusukawa, W. Ando
      Journal : Angew. Chem. Int. Ed. Engl.
      Publication Date : 1996/07
      Volume,Number,Page : 35巻・10号・p1315-1317
    • Co(salen)-Catalyzed tert-Butyl Hydroperoxide Oxidation of tert-Butylphenols Bearing an Unsaturated Side Chain
      Author : K. Maruyama, T. Kusukawa, T. Mashino, A. Nishinaga
      Journal : J. Org. Chem.
      Publication Date : 1996/05
      Volume,Number,Page : 61巻・10号・p3342-3349
    • Photochemical Functionalization of C60 with Cyclosilanes and Cyclogermane
      Author : T. Kusukawa, A. Shike, W. Ando
      Journal : Tetrahedron
      Publication Date : 1996/04
      Volume,Number,Page : 52巻・14号・p4995-5005
    • Photochemical Additions of cyclo-(Ar2Si)4 and (Ar2Ge)4 to C60
      Author : T. Kusukawa, Y. Kabe, W. Ando
      Journal : Organometallics
      Publication Date : 1995/05
      Volume,Number,Page : 14巻・5号・p2142-2144
    • Palladium Catalyzed Disilane Metathesis Reaction of 1,2-Disilacyclobutanes
      Author : T. Kusukawa, Y. Kabe, B. Nestler, W. Ando
      Journal : Organometallics
      Publication Date : 1995/05
      Volume,Number,Page : 14巻・5号・p2556-2564
    • Unusual Rearrangement in the Photochemical Addition of Bis(alkylidene)-disilacyclobutane to C60
      Author : T. Kusukawa, Y. Kabe, T. Erata, B. Nestler, W. Ando
      Journal : Organometallics
      Publication Date : 1994/11
      Volume,Number,Page : 13巻・11号・p4186-4188
    • Transition Metal Catalyzed Reaction of Peralkylated 3,4-Bis(alkylidene)- 1,2-disilacyclobutane
      Author : T. Kusukawa, Y. Kabe, W. Ando
      Journal : Chem. Lett.
      Publication Date : 1993/06
      Volume,Number,Page : 22巻・6号・p985-988
    • Cobalt Schiff Base Complex Catalyzed Dehydrogenation of Amines with t-Butyl Hydroperoxide
      Author : K. Maruyama, T. Kusukawa, Y. Higuchi, A. Nishinaga
      Journal : Chem. Lett.
      Publication Date : 1991/07
      Volume,Number,Page : 20巻・7号・p1093-1096


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